9. Jessica Biel and Justin Timberlake. Cries of 90's worshippers everywhere could be heard when Justin Timberlake and Jessica Biel got married. The pair were married on October 19, 2012 in Italy. Timberlake serenaded his wife while playing the guitar as she walked down the aisle in her gorgeous pink gown. Their celebrations lasted a whole week. 100 guests were attendance.